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- W2002835858 abstract "Two isomeric dimeric steroids, 3,3'-bis(methyl 3-hydroxyandrost-4-en-17-on-19-oate-3-yl), with symmetrical (alpha, alpha') and unsymmetrical structures (alpha,beta'), have been obtained by reduction of methyl androst-4-ene-3,17-dion-19-oate with zinc in aqueous acetic acid together with the major products, the isomeric methyl 5alpha- and 5beta-androst-3-en-17-on-19-oates. The structures of the dimers and unsaturated products are supported by spectroscopic methods. The symmetrical dimer was also obtained from treatment of the 4-en-3-on-19-oate ester with lithium in ammonia." @default.
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- W2002835858 date "2000-04-01" @default.
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- W2002835858 title "Steroid dimer formation: metal reduction of Methyl Androst-4-ene-3,17-dion-19-oate" @default.
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- W2002835858 doi "https://doi.org/10.1016/s0039-128x(99)00108-7" @default.
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