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• W2002882762 abstract "The total synthesis of fully functionalized polyhydroxyamide B,C-seco-analogues of the anticancer compound pancratistatin (PST) (1) is reported. Key steps include an Evans’ MgCl2-promoted anti-aldol reaction between a functionalized l-threose derivative and (R)-(+)-oxazolidinone to stereoselectively form the C-1/C-10b bond and a regiospecific radical-mediated oxidative fragmentation of a 1,3-benzylidene. The B,C-seco compounds 25 and 26 exhibited low activity (ED50 > 30 µg/mL) for inducing apoptosis in human cancer cells." @default.
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• W2002882762 date "2008-01-29" @default.
• W2002882762 modified "2023-09-23" @default.
• W2002882762 title "Synthesis and Biological Evaluation of Fully Functionalized <i>seco</i>-Pancratistatin Analogues" @default.
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• W2002882762 doi "https://doi.org/10.1021/np0705460" @default.
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