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- W2002912691 abstract "Haemoprotein models, whose molecular weight was sufficiently low (3000–15000) to be amenable to polarographic investigation, have been synthesized. Two or three haem units were π-bonded to polyvinyl-imidazole and polyhistidine chains via nitrogen at two co-ordination positions which are perpendicular to the iron-porphyrin network. Oligohaemichromes-and-haemochromes were obtained in which the iron-iron spacing was 15–70 Å. The electroreduction of the oligohaemichromes at the dropping mercury cathode was 15–28 orders of magnitude slower than that of ferrihaem, ceteris paribus. Mechanistic implications are discussed, with emphasis on a plausible electron transfer path." @default.
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- W2002912691 date "1968-01-01" @default.
- W2002912691 modified "2023-09-25" @default.
- W2002912691 title "Polarography and electroreduction of synthetic haemoprotein models" @default.
- W2002912691 doi "https://doi.org/10.1039/df9684500227" @default.
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