Matches in SemOpenAlex for { <https://semopenalex.org/work/W2002915214> ?p ?o ?g. }
Showing items 1 to 82 of
82
with 100 items per page.
- W2002915214 endingPage "775" @default.
- W2002915214 startingPage "763" @default.
- W2002915214 abstract "Reactive scattering of F atoms with C3H5I molecules has been studied at an initial translational energy E ∼ 38 kJ mol-1 using a supersonic beam of F atoms seeded in He buffer gas and at E ∼ 12 kJ mol-1 with Ne buffer gas. The centre-of-mass angular distribution of IF scattering at E ∼ 38 kJ mol -1 shows peaking in the forward and backward directions which is consistent with reaction via a short-lived F-I-C3H5 complex with a lifetime less than one rotational period. The angular distribution at E ∼ 12 kJ mol-1 has a broad peak in the forward direction. The extended microcanonical theory shows that only a minor fraction of scattering at high initial translational energy may be identified with the precessional motion of the F-I-C3H5 product transition state formed in large impact parameter collisions. However, a major fraction of scattering at E ∼ 38 kJ mol-1 and all the scattering at E ∼ 12 kJ mol-1 may be described by phase space theory. The product translational energy distributions indicate that energy is not randomized over internal modes of the intermediate complex in accord with previous laser-induced fluorescence measurements of the IF product vibrational state distribution. However, the overall distribution of internal energy which determines the product angular and translational energy distributions is compatible with the microcanonical distribution for an effective number of internal degrees of freedom." @default.
- W2002915214 created "2016-06-24" @default.
- W2002915214 creator A5027465823 @default.
- W2002915214 creator A5065029598 @default.
- W2002915214 creator A5083229057 @default.
- W2002915214 date "1991-03-01" @default.
- W2002915214 modified "2023-09-24" @default.
- W2002915214 title "Reactive scattering of a supersonic fluorine atom beam: F + C3H5I" @default.
- W2002915214 cites W1581811934 @default.
- W2002915214 cites W1967009830 @default.
- W2002915214 cites W1967441190 @default.
- W2002915214 cites W1974817600 @default.
- W2002915214 cites W1991067437 @default.
- W2002915214 cites W2004722588 @default.
- W2002915214 cites W2006807440 @default.
- W2002915214 cites W2033134877 @default.
- W2002915214 cites W2037763619 @default.
- W2002915214 cites W2040129082 @default.
- W2002915214 cites W2060097178 @default.
- W2002915214 cites W2068910705 @default.
- W2002915214 cites W2072432511 @default.
- W2002915214 cites W2077659938 @default.
- W2002915214 cites W2128078175 @default.
- W2002915214 cites W2144640539 @default.
- W2002915214 cites W4247263983 @default.
- W2002915214 cites W4253395999 @default.
- W2002915214 doi "https://doi.org/10.1080/00268979100100541" @default.
- W2002915214 hasPublicationYear "1991" @default.
- W2002915214 type Work @default.
- W2002915214 sameAs 2002915214 @default.
- W2002915214 citedByCount "6" @default.
- W2002915214 crossrefType "journal-article" @default.
- W2002915214 hasAuthorship W2002915214A5027465823 @default.
- W2002915214 hasAuthorship W2002915214A5065029598 @default.
- W2002915214 hasAuthorship W2002915214A5083229057 @default.
- W2002915214 hasConcept C121332964 @default.
- W2002915214 hasConcept C149635348 @default.
- W2002915214 hasConcept C184779094 @default.
- W2002915214 hasConcept C185592680 @default.
- W2002915214 hasConcept C191486275 @default.
- W2002915214 hasConcept C205991772 @default.
- W2002915214 hasConcept C32909587 @default.
- W2002915214 hasConcept C41008148 @default.
- W2002915214 hasConcept C54419926 @default.
- W2002915214 hasConcept C58312451 @default.
- W2002915214 hasConcept C62520636 @default.
- W2002915214 hasConcept C65494353 @default.
- W2002915214 hasConcept C97355855 @default.
- W2002915214 hasConceptScore W2002915214C121332964 @default.
- W2002915214 hasConceptScore W2002915214C149635348 @default.
- W2002915214 hasConceptScore W2002915214C184779094 @default.
- W2002915214 hasConceptScore W2002915214C185592680 @default.
- W2002915214 hasConceptScore W2002915214C191486275 @default.
- W2002915214 hasConceptScore W2002915214C205991772 @default.
- W2002915214 hasConceptScore W2002915214C32909587 @default.
- W2002915214 hasConceptScore W2002915214C41008148 @default.
- W2002915214 hasConceptScore W2002915214C54419926 @default.
- W2002915214 hasConceptScore W2002915214C58312451 @default.
- W2002915214 hasConceptScore W2002915214C62520636 @default.
- W2002915214 hasConceptScore W2002915214C65494353 @default.
- W2002915214 hasConceptScore W2002915214C97355855 @default.
- W2002915214 hasIssue "4" @default.
- W2002915214 hasLocation W20029152141 @default.
- W2002915214 hasOpenAccess W2002915214 @default.
- W2002915214 hasPrimaryLocation W20029152141 @default.
- W2002915214 hasRelatedWork W1936851581 @default.
- W2002915214 hasRelatedWork W1975442986 @default.
- W2002915214 hasRelatedWork W2053080363 @default.
- W2002915214 hasRelatedWork W2126185722 @default.
- W2002915214 hasRelatedWork W2151182900 @default.
- W2002915214 hasRelatedWork W2271414796 @default.
- W2002915214 hasRelatedWork W4233894821 @default.
- W2002915214 hasRelatedWork W4242901009 @default.
- W2002915214 hasRelatedWork W4251857104 @default.
- W2002915214 hasRelatedWork W4361016854 @default.
- W2002915214 hasVolume "72" @default.
- W2002915214 isParatext "false" @default.
- W2002915214 isRetracted "false" @default.
- W2002915214 magId "2002915214" @default.
- W2002915214 workType "article" @default.