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• W2002931552 abstract "The ultraviolet photoelectron spectra (UPS) of 11 monosubstituted and 25 disubstituted aliphatic alkynes have been recorded using He(I) radiation. The inductive effects of 15 saturated alkyl substituents on the first ionisation potential (emission of a photoelectron from a π orbital of the triple bond) were studied, and correlated with Taft's polar constants (σ*). An attribution of the second ionisation potential has been proposed, which accords with previous experimental results on both alkenes and carbonyl compounds. Some vibrational frequencies of molecular ions have been determined for the least-branched 15 alkynes." @default.
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• W2002931552 date "1975-01-01" @default.
• W2002931552 modified "2023-10-16" @default.
• W2002931552 title "Spectres de photoelectrons des alcynes" @default.
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• W2002931552 doi "https://doi.org/10.1016/0368-2048(75)80055-7" @default.
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