Matches in SemOpenAlex for { <https://semopenalex.org/work/W2002943616> ?p ?o ?g. }
- W2002943616 abstract "Abstract A series fo adenine N(1)-oxide (LH) complexes with 3d metal perchlorates were prepared by refluxing mixtures of ligand and salt in ethanol-triethyl orthoformate. Charaterization studies revealed significant differences in ligand binding sites and probable complex structural types, with metal ion variation. Thus, [Cr(LH)2(OClO3)2(EtOH)2(ClO4) and [M(LH)2(OClO3)(EtOH)2](ClO4) (M = Mn, Zn) seem to be monomeric with unidentate, imidazole nitrogen-bonded (most porbably N(7) LH, while the Co2+ analogue of the latter two complexes is apparently a linear polymer, with single bridges of bidentate O(1), N(7)-bonded LH, as well as terminal unidentate imidazole introgen-bonded ligand groups. The rest of the complexes involve both neutral LH and anionic L− ligands. The subnormal room temperature magnetic moment of the Cu2+ complex (1.68 μB) favours a triple ligand-briged structure of the [(O3ClO)Cu(LH)L2Cu(OClO3)] type, with O(1), N(7)-bonded bridging ligands. Ni(LH)L(ClO4)·2EtOH and Fe(LH)2L(ClO4)2 were considered as linear polymers, with single bridges of O(1) N(7)-bonded adenine N(1)-oxide ligands; the rest of the ligands present seem to be terminal, unidentate imidazole nitroten-bonded for M = Ni2+ and bidentate chelating, O(1), N(6)-bonded for M = Fe3+." @default.
- W2002943616 created "2016-06-24" @default.
- W2002943616 creator A5022746656 @default.
- W2002943616 creator A5024194641 @default.
- W2002943616 creator A5037166983 @default.
- W2002943616 creator A5052066978 @default.
- W2002943616 creator A5058323461 @default.
- W2002943616 creator A5074171774 @default.
- W2002943616 creator A5076075919 @default.
- W2002943616 date "1981-01-01" @default.
- W2002943616 modified "2023-09-27" @default.
- W2002943616 title "Adennine N(1)-oxide complexes with first row transition metal perchlorates" @default.
- W2002943616 cites W1510107227 @default.
- W2002943616 cites W1511464125 @default.
- W2002943616 cites W1518724681 @default.
- W2002943616 cites W1567179372 @default.
- W2002943616 cites W1584150660 @default.
- W2002943616 cites W1586721915 @default.
- W2002943616 cites W1587441483 @default.
- W2002943616 cites W1596758867 @default.
- W2002943616 cites W1817591575 @default.
- W2002943616 cites W1963882710 @default.
- W2002943616 cites W1971801208 @default.
- W2002943616 cites W1972149874 @default.
- W2002943616 cites W1973175723 @default.
- W2002943616 cites W1974009675 @default.
- W2002943616 cites W1974564807 @default.
- W2002943616 cites W1976847129 @default.
- W2002943616 cites W1977415287 @default.
- W2002943616 cites W1977544405 @default.
- W2002943616 cites W1982123637 @default.
- W2002943616 cites W1986228741 @default.
- W2002943616 cites W1995210893 @default.
- W2002943616 cites W1996584224 @default.
- W2002943616 cites W1996691278 @default.
- W2002943616 cites W1999175966 @default.
- W2002943616 cites W2004725861 @default.
- W2002943616 cites W2004831865 @default.
- W2002943616 cites W2005152863 @default.
- W2002943616 cites W2011843235 @default.
- W2002943616 cites W2013128962 @default.
- W2002943616 cites W2014908042 @default.
- W2002943616 cites W2015165171 @default.
- W2002943616 cites W2022171710 @default.
- W2002943616 cites W2028593714 @default.
- W2002943616 cites W2030435065 @default.
- W2002943616 cites W2030843464 @default.
- W2002943616 cites W2031644164 @default.
- W2002943616 cites W2039598446 @default.
- W2002943616 cites W2039691881 @default.
- W2002943616 cites W2040176506 @default.
- W2002943616 cites W2042168356 @default.
- W2002943616 cites W2051866840 @default.
- W2002943616 cites W2055058265 @default.
- W2002943616 cites W2055247248 @default.
- W2002943616 cites W2055928036 @default.
- W2002943616 cites W2058020753 @default.
- W2002943616 cites W2059125888 @default.
- W2002943616 cites W2065537930 @default.
- W2002943616 cites W2066016916 @default.
- W2002943616 cites W2069533858 @default.
- W2002943616 cites W2069907620 @default.
- W2002943616 cites W2070767735 @default.
- W2002943616 cites W2077172408 @default.
- W2002943616 cites W2077534030 @default.
- W2002943616 cites W2078090595 @default.
- W2002943616 cites W2078662097 @default.
- W2002943616 cites W2080977523 @default.
- W2002943616 cites W2084284754 @default.
- W2002943616 cites W2084544057 @default.
- W2002943616 cites W2088363375 @default.
- W2002943616 cites W2094286431 @default.
- W2002943616 cites W2104884834 @default.
- W2002943616 cites W2124915872 @default.
- W2002943616 cites W2144603306 @default.
- W2002943616 cites W2314970058 @default.
- W2002943616 cites W2315419658 @default.
- W2002943616 cites W2325188798 @default.
- W2002943616 cites W2325386721 @default.
- W2002943616 cites W2327492156 @default.
- W2002943616 cites W2327652021 @default.
- W2002943616 cites W2328413510 @default.
- W2002943616 cites W2330070868 @default.
- W2002943616 cites W2330338072 @default.
- W2002943616 cites W2334609754 @default.
- W2002943616 cites W2623556278 @default.
- W2002943616 cites W2921854689 @default.
- W2002943616 cites W2949933216 @default.
- W2002943616 cites W2951847068 @default.
- W2002943616 cites W2991970453 @default.
- W2002943616 cites W3139070534 @default.
- W2002943616 cites W88324658 @default.
- W2002943616 doi "https://doi.org/10.1016/s0020-1693(00)88562-x" @default.
- W2002943616 hasPublicationYear "1981" @default.
- W2002943616 type Work @default.
- W2002943616 sameAs 2002943616 @default.
- W2002943616 citedByCount "19" @default.
- W2002943616 crossrefType "journal-article" @default.
- W2002943616 hasAuthorship W2002943616A5022746656 @default.
- W2002943616 hasAuthorship W2002943616A5024194641 @default.