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- W2002949323 abstract "The interaction of tetracycline and oxovanadium(IV) in aqueous solution was studied by potentiometric and spectrophotometric methods. Oxovanadium(IV) ions form both a positively charged 1:1 and a neutral 2:1 metal-ligand complex with tetracycline. When a 1:1 ligand-to-metal ratio mixture is used at about pH 4.5 the 1:1 species predominates, being replaced at pH 6 by the binuclear complex. The binuclear complex has been isolated and fully characterised. Infrared and EPR studies suggest the existence of two distinct vanadyl binding sites. Our results indicate that the first vanadium coordinates to the BCD-ring system and the second one to the A-ring. Biological implications of the existence of a neutral complex at physiological pH are briefly discussed." @default.
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- W2002949323 date "1999-09-01" @default.
- W2002949323 modified "2023-09-26" @default.
- W2002949323 title "A physicochemical study of the tetracycline coordination to oxovanadium(IV)" @default.
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- W2002949323 doi "https://doi.org/10.1016/s0162-0134(99)00130-0" @default.
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