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- W2003007010 abstract "A study has been made of the effect of density on the radiolysis of n-butane at 170°C over the density region 0.006–0.575 g. cc−1. While G(H2) and G(C2H6) are not affected by the density change, G(CH4) and G(C3H8) decrease sharply in the density region from 0 to 0.1 g. cc−1. The latter facts may be interpreted in terms of the collisional deactivation of the excited ion. The rate constant of the fragmentation of the butane ion has been estimated from the deactivation-fragmentation competition scheme and compared with the rate constant calculated from the quasi-equilibrium theory. Agreement is satisfactory. The formation of methane by ionic fragmentation near the critical state has also been considered." @default.
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- W2003007010 date "1965-05-01" @default.
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- W2003007010 title "Effect of Density in the Radiolysis ofn-Butane" @default.
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