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- W2003009488 abstract "Abstract Novel hetero‐π‐conjugated compounds (dibenzochalcogenaborins) with the same molecular framework, bearing a boron atom as an acceptor and chalcogen atoms as a donor, were synthesized, and systematic comparisons among these molecules were performed. X‐ray crystallographic analysis of these molecules showed similar structures with high planarity. UV/Vis spectroscopy and theoretical calculations revealed that the absorption maxima and the HOMO–LUMO gap changed by systematically changing the bridging chalcogen atom. Dibenzooxaborin and dibenzothiaborin showed fluorescence emission both in solution and in the solid state with a small Stokes shift, indicating the high rigidity of these compounds. On the other hand, dibenzoselenaborin exhibited a very weak fluorescence as a result of the heavy atom effect." @default.
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- W2003009488 date "2008-12-23" @default.
- W2003009488 modified "2023-10-07" @default.
- W2003009488 title "Synthesis of Dibenzochalcogenaborins and Systematic Comparisons of Their Optical Properties by Changing a Bridging Chalcogen Atom" @default.
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- W2003009488 doi "https://doi.org/10.1002/asia.200800302" @default.
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