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- W2003010922 abstract "The use of a mixture of dl- and meso-divinylethylene carbonate as an electrophile in palladium-catalyzed asymmetric allylic alkylation reactions is reported. From the diastereomeric mixture of meso and chiral racemic starting materials, a single product is obtained in high optical purity employing either oxygen or nitrogen nucleophiles. The resulting dienes have proven to be versatile synthetic intermediates as each carbon is functionalized for further transformation and differentiated by virtue of the reaction. A mechanism for this intriguing transformation is proposed and a concise enantioselective total synthesis of (+)-australine hydrochloride is reported as well as a formal synthesis of isoaltholactone." @default.
- W2003010922 created "2016-06-24" @default.
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- W2003010922 creator A5052486739 @default.
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- W2003010922 date "2007-11-16" @default.
- W2003010922 modified "2023-10-17" @default.
- W2003010922 title "A Convergent Pd-Catalyzed Asymmetric Allylic Alkylation ofdl- andmeso-Divinylethylene Carbonate: Enantioselective Synthesis of (+)-Australine Hydrochloride and Formal Synthesis of Isoaltholactone" @default.
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- W2003010922 doi "https://doi.org/10.1002/chem.200700832" @default.
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