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- W2003011968 abstract "Crystals of Pt2Cl4(AsMe3)2 are monoclinic, space group P21/n, a= 10·39, b= 11·84, c= 6·74 Å, β= 94·33°. The dimeric molecule consists of two square-planar platinum moieties sharing an edge, with the platinum atoms bridged unsymmetrically by two chlorine atoms. The crystal site symmetry is (Ci), but the molecule approximates very closely to 2/m(C2h) point symmetry. The Pt–Cl bond length trans to arsenic is 2·39 Å, longer than the two normal Pt–Cl bond lengths by ca. 0·1 Å, while the Pt–As bond length of 2·31 Å is much shorter than expected. These observations are a consequence of the strong trans-influence of trimethylarsine." @default.
- W2003011968 created "2016-06-24" @default.
- W2003011968 creator A5008942233 @default.
- W2003011968 date "1970-01-01" @default.
- W2003011968 modified "2023-10-18" @default.
- W2003011968 title "Crystal and molecular structure of di-µ-chloro-[dichlorobis(trimethylarsine)]platinum(<scp>II</scp>); a quantitative assessment of the trans-influence of the trimethylarsine ligand" @default.
- W2003011968 doi "https://doi.org/10.1039/j19700000168" @default.
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