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• W2003016175 abstract "The ligands HN(CH2−2-C5H4N)2, BPMA, and PhCH2N(CH2−2-C5H4N)2, BBPMA, react with Na[AuCl4] to give the cationic complexes [AuCl(BPMA−H)]+ and [AuCl(BBPMA)]2+, respectively. The amido complex [AuCl(BPMA−H)]+ undergoes easy inversion at the amido nitrogen atom and can be reversibly protonated by triflic acid to give [AuCl(BPMA)]2+. The complex [AuCl(BBPMA)]2+ is easily decomposed in aqueous solution by cleavage of a carbon−nitrogen bond or, in dilute HCl solution, by protonation of the ligand to give [BBPMAH2]Cl[AuCl4] The complexes [BBPMAH2]Cl[AuCl4] and [BBPMAH2]Cl[AuCl2] can be formed by direct reaction of BBPMA with H[AuCl4]. Unusual forms of gold(III)···gold(III) and gold(III)···gold(I) aurophilic bonding are observed in the salts [AuCl(BPMA−H)][PF6] and [AuCl(BPMA−H)][AuCl2], respectively. The first comparison of the structures of gold(III) amine and amido complexes, in the cations [AuCl(BPMA−H)]+ and [AuCl(BPMA)]2+, indicates that there is little pπ−dπ bonding in the amido−gold bond and that the amide exerts a stronger trans influence than the amine group." @default.
• W2003016175 created "2016-06-24" @default.
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• W2003016175 date "2007-01-17" @default.
• W2003016175 modified "2023-10-18" @default.
• W2003016175 title "Amine−Amide Equilibrium in Gold(III) Complexes and a Gold(III)−Gold(I) Aurophilic Bond" @default.
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• W2003016175 doi "https://doi.org/10.1021/ic061911y" @default.
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