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- W2003035634 abstract "Equations for the calculation of the Kirkwood–Buff integrals (KBI) for the components of a ternary system from thermodynamic data are presented and applied to a number of mixtures of non-electrolytes. The mixtures comprise substances which may develope strong mutual interactions due to e.g. permanent dipoles and hydrogen bonds; they are: (I) water–propan-1-ol–N,N-dimethylformamide (DMF), (II) water–ethane-1,2-diol–acetonitrile, (III) water–ethane-1,2-diol–ethanol, (IV) ethanol–trichloromethane–1,4-dioxane; the system (V), water–propanol–urea, previously studied is also discussed. The observed KBIs have been correlated to interactions among functional groups and to the structure of the solvent components. Moreover, a preferential solvation coefficient of a given compound with respect to the other two is given a different definition to that of previous authors and calculated; its change with changing concentration of solvating components is examined. These quantities have proved to be useful indicators of the predominant types of interactions in various concentration regions." @default.
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- W2003035634 title "Kirkwood–Buff integrals and preferential solvation in ternary non-electrolyte mixtures" @default.
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- W2003035634 doi "https://doi.org/10.1039/ft9959100431" @default.
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