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- W2003044833 abstract "A method is described for determining the coupling parameters (force constants) in b.c.c. and f.c.c. solid solutions from measurements of the elastic constants and the diffuse X-ray intensity scattered by static atomic displacements in the solid solution. Both measurements can be made on the same single crystal, the diffuse intensity measurements consisting of radial scans (varying 2Ω only) along the [100], [110], and [111] reciprocal lattice directions. The analysis of the diffuse intensity allows the scattering due to thermal lattice vibrations to be eliminated from measurements at one temperature. With this method, it is possible to determine all of the coupling parameters of the first three coordination shells in b.c.c. solid solutions, while it is necessary to assume that some of the coupling parameters are dependent variables in order to determine the coupling parameters of the first three coordination shells in f.c.c. solid solutions. If one assumes that the third-nearest neighbor forces in the f.c.c. lattice are central forces, it can be shown that one need know the diffuse intensity along only the [100] and [110] directions in order to determine the remaining independent coupling parameters of the first three coordination shells. The proposed method is applicable to concentrated solid solutions where there are large mass differences in the solute and solvent atoms and where the interaction distances are short-range in nature." @default.
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- W2003044833 date "1971-01-01" @default.
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- W2003044833 title "The determination of atomic force constants in cubic solid solutions—I. Theory" @default.
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- W2003044833 doi "https://doi.org/10.1016/s0022-3697(71)80177-4" @default.
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