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- W2003048255 abstract "Abstract The mechanism of solute retention in gas—liquid chromatography was studied by using silica gel coated with different amounts of polyethylene glycol 20 000 (PEG 20M). The retention volumes of aliphatic hydrocarbons, aromatic hydrocarbons and dialkyl ethers were determined as a function of liquid phase loading. The silica gel surface showed homogeneous characteristics on adsorption of saturated hydrocarbons and a heterogeneous nature on adsorption of the other solutes. The experimental data could be interpreted on the basis of a model in which the silica gel surface was covered first with a monolayer and then with a double layer of PEG 20M. Distribution constants of adsorption on the silica gel, on the monolayer and on the double layer were calculated." @default.
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- W2003048255 date "1990-01-01" @default.
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- W2003048255 title "Adsorption effect on the retention volume of hydrocarbons and dialkyl ethers in gas—liquid chromatography using a polar stationary phase and silica gel support" @default.
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- W2003048255 doi "https://doi.org/10.1016/s0021-9673(01)81488-6" @default.
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