FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2003048647> ?p ?o ?g. }

• W2003048647 endingPage "2017" @default.
• W2003048647 startingPage "2009" @default.
• W2003048647 abstract "Electron mobility μ0 in nonpolar and slightly polar (D≤0.5 D) hydrocarbon fluids is strongly affected by the external shape of the molecules. The mobility is large in a liquid of spherelike molecules such as neopentane. Addition of rodlike molecules such as n-pentane decreases μ0, but has little effect on the value of the threshold field for electron heating. A liquid of spherelike molecules forms a conduction band that has relatively small undulations in its lower potential surface. Addition of rodlike molecules provides orientational disorder, anisotropic polarizability, and restricted rotation, which in combination produce potential fluctuations that are durable enough to localized electrons. The maximum in μ0 that occurs in pure liquid neopentane at 3.5×1027 molecule/m3 progressively decreases in magnitude and shifts to lower densities as n-pentane is added; it occurs at the critical density in n-pentane. A plot of log μ0 against mol % n-pentane for liquid mixtures of n- and neo-pentane at constant T/Tc is slightly S shaped. A plot of the Arrhenius temperature coefficient Eμ against mole % n-pentane is S shaped in the opposite direction. At T/Tc=0.999 the log μ0 plot is not S shape and the slope is much smaller than at T/Tc≤0.92; the molecular shape effect is minimal in the critical fluids and dense gases, 1.0≥n/nc≥0.3. Quasilocalization occurs to a similar extent in all gases at the same n/nc and T/Tc. In the low density gases the molecular shape effect is the opposite of that in dense liquids; at electron energies &lt;0.10 eV the spherelike neopentane has a larger scattering cross section than does its nonspherelike isomer n-pentane. In an equimolar mixture the stronger scatterer dominates the electron behavior, which means n-pentane in the liquid and neopentane in the normal gas." @default.
• W2003048647 created "2016-06-24" @default.
• W2003048647 creator A5058195120 @default.
• W2003048647 creator A5087293993 @default.
• W2003048647 creator A5089221229 @default.
• W2003048647 date "1983-08-15" @default.
• W2003048647 modified "2023-10-18" @default.
• W2003048647 title "Molecular shape effect on electron transport in fluids: Density and temperature studies in mixtures ofn‐pentane and neopentane" @default.
• W2003048647 cites W1536908509 @default.
• W2003048647 cites W1967248581 @default.
• W2003048647 cites W1989693271 @default.
• W2003048647 cites W1994513521 @default.
• W2003048647 cites W1997138498 @default.
• W2003048647 cites W1999329392 @default.
• W2003048647 cites W1999679823 @default.
• W2003048647 cites W1999942516 @default.
• W2003048647 cites W2003026437 @default.
• W2003048647 cites W2007806522 @default.
• W2003048647 cites W2012559734 @default.
• W2003048647 cites W2022458844 @default.
• W2003048647 cites W2035494373 @default.
• W2003048647 cites W2048784226 @default.
• W2003048647 cites W2049879885 @default.
• W2003048647 cites W2054500972 @default.
• W2003048647 cites W2055528621 @default.
• W2003048647 cites W2059355963 @default.
• W2003048647 cites W2060809376 @default.
• W2003048647 cites W2061034421 @default.
• W2003048647 cites W2072604829 @default.
• W2003048647 cites W2077387531 @default.
• W2003048647 cites W2078118504 @default.
• W2003048647 cites W2079407397 @default.
• W2003048647 cites W2083290205 @default.
• W2003048647 cites W2084358061 @default.
• W2003048647 cites W2085386290 @default.
• W2003048647 cites W2094556656 @default.
• W2003048647 cites W2094748298 @default.
• W2003048647 cites W2094884653 @default.
• W2003048647 cites W2129100657 @default.
• W2003048647 cites W2161856092 @default.
• W2003048647 cites W2614548639 @default.
• W2003048647 cites W4231552445 @default.
• W2003048647 cites W4238555739 @default.
• W2003048647 cites W4247914367 @default.
• W2003048647 doi "https://doi.org/10.1063/1.445985" @default.
• W2003048647 hasPublicationYear "1983" @default.
• W2003048647 type Work @default.
• W2003048647 sameAs 2003048647 @default.
• W2003048647 citedByCount "10" @default.
• W2003048647 crossrefType "journal-article" @default.
• W2003048647 hasAuthorship W2003048647A5058195120 @default.
• W2003048647 hasAuthorship W2003048647A5087293993 @default.
• W2003048647 hasAuthorship W2003048647A5089221229 @default.
• W2003048647 hasConcept C113196181 @default.
• W2003048647 hasConcept C121332964 @default.
• W2003048647 hasConcept C147789679 @default.
• W2003048647 hasConcept C161790260 @default.
• W2003048647 hasConcept C178790620 @default.
• W2003048647 hasConcept C185592680 @default.
• W2003048647 hasConcept C2777207669 @default.
• W2003048647 hasConcept C2777589835 @default.
• W2003048647 hasConcept C2777949474 @default.
• W2003048647 hasConcept C2778556512 @default.
• W2003048647 hasConcept C2779211955 @default.
• W2003048647 hasConcept C32909587 @default.
• W2003048647 hasConcept C8739425 @default.
• W2003048647 hasConcept C95121573 @default.
• W2003048647 hasConcept C97355855 @default.
• W2003048647 hasConceptScore W2003048647C113196181 @default.
• W2003048647 hasConceptScore W2003048647C121332964 @default.
• W2003048647 hasConceptScore W2003048647C147789679 @default.
• W2003048647 hasConceptScore W2003048647C161790260 @default.
• W2003048647 hasConceptScore W2003048647C178790620 @default.
• W2003048647 hasConceptScore W2003048647C185592680 @default.
• W2003048647 hasConceptScore W2003048647C2777207669 @default.
• W2003048647 hasConceptScore W2003048647C2777589835 @default.
• W2003048647 hasConceptScore W2003048647C2777949474 @default.
• W2003048647 hasConceptScore W2003048647C2778556512 @default.
• W2003048647 hasConceptScore W2003048647C2779211955 @default.
• W2003048647 hasConceptScore W2003048647C32909587 @default.
• W2003048647 hasConceptScore W2003048647C8739425 @default.
• W2003048647 hasConceptScore W2003048647C95121573 @default.
• W2003048647 hasConceptScore W2003048647C97355855 @default.
• W2003048647 hasIssue "4" @default.
• W2003048647 hasLocation W20030486471 @default.
• W2003048647 hasOpenAccess W2003048647 @default.
• W2003048647 hasPrimaryLocation W20030486471 @default.
• W2003048647 hasRelatedWork W1964356362 @default.
• W2003048647 hasRelatedWork W1972572797 @default.
• W2003048647 hasRelatedWork W2003048647 @default.
• W2003048647 hasRelatedWork W2034526069 @default.
• W2003048647 hasRelatedWork W2048983865 @default.
• W2003048647 hasRelatedWork W2055794155 @default.
• W2003048647 hasRelatedWork W2067599456 @default.
• W2003048647 hasRelatedWork W2077323848 @default.
• W2003048647 hasRelatedWork W2082339410 @default.
• W2003048647 hasRelatedWork W4245099818 @default.
• W2003048647 hasVolume "79" @default.

• next