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- W2003048995 abstract "The reactions of HgE (E=S, Se) with HgX2 and MX4 (M=Zr, Hf; X=Cl, Br) in evacuated glass ampoules lead to a series of isotypic compounds of the general formula Hg3E2[MX6] in the form of colorless (X=Cl) and light-yellow (X=Br) air-sensitive crystals. The crystal structures of Hg3S2[ZrCl6] (I), Hg3S2[HfCl6] (II), Hg3Se2[ZrCl6] (III), Hg3Se2[HfCl6] (IV), Hg3S2[ZrBr6] (V), and Hg3Se2[ZrBr6] (VI) were refined based on single-crystal data. All compounds crystallize in the monoclinic space group P21/a with the lattice parameters a=662.18(2) pm, b=734.97(3) pm, c=1290.83(5) pm, β=91.755(2)° for (I) and and a=701.97(3) pm, b=756.79(3) pm, c=1350.99(6) pm, β=92.164(3)° for (VI). The structures are built of (Hg3E2)2+ layers stacked perpendicular to the c-axis. The polycationic layers consist of two-dimensionally linked 12-membered Hg6E6 rings in the chair conformation with linear coordinated Hg and trigonal pyramidal coordinated chalcogen atoms. Almost regular octahedral [MX6]2− ions are embedded between the layers. This arrangement is closely related to the structure of Hg3S2[SiF6], which represents a higher symmetric congener. The structure relation is discussed using the supergroup–subgroup relation between space groups." @default.
- W2003048995 created "2016-06-24" @default.
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- W2003048995 date "2003-04-01" @default.
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- W2003048995 title "Expanded polycationic mercury–chalcogen networks in the layered compounds Hg3E2[MX6] (E=S, Se; M=Zr, Hf; X=Cl, Br)" @default.
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- W2003048995 doi "https://doi.org/10.1016/s0022-4596(02)00027-0" @default.
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