FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2003062639> ?p ?o ?g. }

• W2003062639 endingPage "1149" @default.
• W2003062639 startingPage "1131" @default.
• W2003062639 abstract "The dissociative chemisorption of oxygen on W(110) has been studied using molecular beam techniques. Chemisorption probabilities have been measured as a function of incidence angle, θi, and kinetic energy, Ei, and of surface coverage and temperature. In addition, angular scattering distributions have been measured for a range of conditions and LEED has been used to examine surface structure. The initial (zero coverage limit) sticking probability is found to depend strongly on the incidence energy, scaling with En=Ei cos2 θi. This probability is ∼10% at En =0.1 eV, rising to essentially unity above En =0.4 eV. At half a monolayer coverage of atomic oxygen, the sticking probability is close to zero up to a threshold of ∼0.25 eV, above which it rises to over 50% by 1.3 eV. In most cases, the sticking probability is found to fall roughly linearly with increasing surface coverage. However, a less‐than‐linear fall‐off is observed for En ≥1 eV and for En ≤0.03 eV, the sticking probability actually rises with increasing coverage reaching a maximum at ∼0.2 ML. These results indicate that while dissociation may proceed via a classical precursor at the lowest energies, such a state can play little rolefor En≥0.1 eV. For En≤0.3 eV, the chemisorption probability falls to less than 5% for a coverage of about 0.5 ML; however, this apparent saturation coverage rises to 0.75 ML at ∼0.25 eV and to about 1.0 ML at about 0.85 eV. These ‘‘favored’’ coverages of 0.5, 0.75, and 1.0 ML are found to be associated with p(2×1), p(2×2), and p(1×1) LEED patterns, respectively. Angular scattering distributions recorded with a differentially pumped rotatable mass spectrometer, revealed predominantly quasispecular peaks, and velocity distributions are also characteristic of direct‐inelastic scattering. The variation of the sticking probability with En is analyzed to obtain barrier height distributions for the clean and half‐covered surfaces and these results are used to predict the sticking probability as a function of coverage and also to predict the initial sticking probability for adsorption from ambient gas or an effusive molecular beam. Reasonable agreement is obtained with available data in each case." @default.
• W2003062639 created "2016-06-24" @default.
• W2003062639 creator A5003685354 @default.
• W2003062639 creator A5046827479 @default.
• W2003062639 creator A5049857121 @default.
• W2003062639 date "1986-07-15" @default.
• W2003062639 modified "2023-10-16" @default.
• W2003062639 title "Effect of incidence kinetic energy and surface coverage on the dissociative chemisorption of oxygen on W(110)" @default.
• W2003062639 cites W1497268071 @default.
• W2003062639 cites W1977068350 @default.
• W2003062639 cites W1978985583 @default.
• W2003062639 cites W1983145976 @default.
• W2003062639 cites W1983157709 @default.
• W2003062639 cites W1983940509 @default.
• W2003062639 cites W1988800609 @default.
• W2003062639 cites W1995930838 @default.
• W2003062639 cites W2006311592 @default.
• W2003062639 cites W2006400091 @default.
• W2003062639 cites W2007973840 @default.
• W2003062639 cites W2008932633 @default.
• W2003062639 cites W2009301896 @default.
• W2003062639 cites W2014131758 @default.
• W2003062639 cites W2016116054 @default.
• W2003062639 cites W2027818072 @default.
• W2003062639 cites W2030220386 @default.
• W2003062639 cites W2030946611 @default.
• W2003062639 cites W2033389881 @default.
• W2003062639 cites W2046526256 @default.
• W2003062639 cites W2048353665 @default.
• W2003062639 cites W2050114226 @default.
• W2003062639 cites W2052472643 @default.
• W2003062639 cites W2052990095 @default.
• W2003062639 cites W2054699181 @default.
• W2003062639 cites W2060793627 @default.
• W2003062639 cites W2071330627 @default.
• W2003062639 cites W2075204595 @default.
• W2003062639 cites W2077702440 @default.
• W2003062639 cites W2080514759 @default.
• W2003062639 cites W2081468905 @default.
• W2003062639 cites W2093826356 @default.
• W2003062639 cites W2095067255 @default.
• W2003062639 cites W2324561798 @default.
• W2003062639 cites W4251471406 @default.
• W2003062639 cites W1978332834 @default.
• W2003062639 doi "https://doi.org/10.1063/1.451310" @default.
• W2003062639 hasPublicationYear "1986" @default.
• W2003062639 type Work @default.
• W2003062639 sameAs 2003062639 @default.
• W2003062639 citedByCount "194" @default.
• W2003062639 countsByYear W20030626392012 @default.
• W2003062639 countsByYear W20030626392013 @default.
• W2003062639 countsByYear W20030626392014 @default.
• W2003062639 countsByYear W20030626392015 @default.
• W2003062639 countsByYear W20030626392016 @default.
• W2003062639 countsByYear W20030626392017 @default.
• W2003062639 countsByYear W20030626392018 @default.
• W2003062639 countsByYear W20030626392021 @default.
• W2003062639 countsByYear W20030626392022 @default.
• W2003062639 countsByYear W20030626392023 @default.
• W2003062639 crossrefType "journal-article" @default.
• W2003062639 hasAuthorship W2003062639A5003685354 @default.
• W2003062639 hasAuthorship W2003062639A5046827479 @default.
• W2003062639 hasAuthorship W2003062639A5049857121 @default.
• W2003062639 hasConcept C102931765 @default.
• W2003062639 hasConcept C114614502 @default.
• W2003062639 hasConcept C121332964 @default.
• W2003062639 hasConcept C135889238 @default.
• W2003062639 hasConcept C147789679 @default.
• W2003062639 hasConcept C150394285 @default.
• W2003062639 hasConcept C162711632 @default.
• W2003062639 hasConcept C178790620 @default.
• W2003062639 hasConcept C184779094 @default.
• W2003062639 hasConcept C185592680 @default.
• W2003062639 hasConcept C2779758070 @default.
• W2003062639 hasConcept C32909587 @default.
• W2003062639 hasConcept C33790079 @default.
• W2003062639 hasConcept C33923547 @default.
• W2003062639 hasConcept C540031477 @default.
• W2003062639 hasConcept C54419926 @default.
• W2003062639 hasConcept C62520636 @default.
• W2003062639 hasConcept C9930424 @default.
• W2003062639 hasConcept C9950777 @default.
• W2003062639 hasConceptScore W2003062639C102931765 @default.
• W2003062639 hasConceptScore W2003062639C114614502 @default.
• W2003062639 hasConceptScore W2003062639C121332964 @default.
• W2003062639 hasConceptScore W2003062639C135889238 @default.
• W2003062639 hasConceptScore W2003062639C147789679 @default.
• W2003062639 hasConceptScore W2003062639C150394285 @default.
• W2003062639 hasConceptScore W2003062639C162711632 @default.
• W2003062639 hasConceptScore W2003062639C178790620 @default.
• W2003062639 hasConceptScore W2003062639C184779094 @default.
• W2003062639 hasConceptScore W2003062639C185592680 @default.
• W2003062639 hasConceptScore W2003062639C2779758070 @default.
• W2003062639 hasConceptScore W2003062639C32909587 @default.
• W2003062639 hasConceptScore W2003062639C33790079 @default.
• W2003062639 hasConceptScore W2003062639C33923547 @default.
• W2003062639 hasConceptScore W2003062639C540031477 @default.
• W2003062639 hasConceptScore W2003062639C54419926 @default.

• next