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• W2003071644 endingPage "6099" @default.
• W2003071644 startingPage "6092" @default.
• W2003071644 abstract "The complex framework [Ru(tpy)(dpk)]2+ has been used to study the generation and reactivity of the nitrosyl complex [Ru(tpy)(dpk)(NO)]3+ ([4]3+). Stepwise conversion of the chloro complex [Ru(tpy)(dpk)(Cl)]+ ([1]+) via [Ru(tpy)(dpk)(CH3CN)]2+ ([2]2+) and the nitro compound [Ru(tpy)(dpk)(NO2)]+ ([3]+) yielded [4]3+; all four complexes were structurally characterized as perchlorates. Electrochemical oxidation and reduction was investigated as a function of the monodentate ligand as was the IR and UV−vis spectroscopic response (absorption/emission). The kinetics of the conversion [4]3+/[3]+ in aqueous environment were also studied. Two-step reduction of [4]3+ was monitored via EPR, UV−vis, and IR (ν(NO), ν(CO)) spectroelectrochemistry to confirm the {RuNO}7 configuration of [4]2+ and to exhibit a relatively intense band at 505 nm for [4]+, attributed to a ligand-to-ligand transition originating from bound NO-." @default.
• W2003071644 created "2016-06-24" @default.
• W2003071644 creator A5007237862 @default.
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• W2003071644 creator A5020043051 @default.
• W2003071644 creator A5020335865 @default.
• W2003071644 creator A5030295049 @default.
• W2003071644 creator A5062826786 @default.
• W2003071644 creator A5085292862 @default.
• W2003071644 date "2005-07-21" @default.
• W2003071644 modified "2023-10-16" @default.
• W2003071644 title "Complex Series [Ru(tpy)(dpk)(X)]<i>ⁿ</i>⁺ (tpy = 2,2‘:6‘,2‘ ‘-Terpyridine; dpk = 2,2‘-Dipyridyl Ketone; X = Cl^-, CH₃CN, NO₂^-, NO⁺, NO^•, NO^-): Substitution and Electron Transfer, Structure, and Spectroscopy" @default.
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• W2003071644 doi "https://doi.org/10.1021/ic050533e" @default.
• W2003071644 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/16097830" @default.
• W2003071644 hasPublicationYear "2005" @default.
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