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- W2003082203 abstract "A novel heteropolyanion-based sulfated ionic liquid (HIL-[Ch-OSO3H]3W12PO40) was prepared by pairing sulfate functionalized cholinium cation [N,N,N-trimethyl-2-(sulfooxy)ethanaminium] with catalytically active phosphotungstic acid anion (W12PO403−). It was characterized by 1H NMR, FT-IR, EDX, XRD, TGA and elemental analysis. Catalytic activity of thus prepared HIL was studied in N-formylation of amines under solvent-free grinding condition. The methodology provided cleaner conversion over shorter reaction time with high turnover frequency (TOF) and chemoselectivity." @default.
- W2003082203 created "2016-06-24" @default.
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- W2003082203 date "2014-09-01" @default.
- W2003082203 modified "2023-09-26" @default.
- W2003082203 title "Heteropolyanion-based sulfated ionic liquid catalyzed formamides synthesis by grindstone chemistry" @default.
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- W2003082203 doi "https://doi.org/10.1016/j.molcata.2014.04.005" @default.
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