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• W2003085274 abstract "The structural and electrochemical properties of manganese dioxide with 3 × 3 tunnels bearing the crystallographic structure of the mineral todorokite were investigated for use as a new cathode material for zinc ion cells. The large 3 × 3 tunnel of todorokite facilitates fast Zn2+ diffusion to the inner region of a particle compared to the conventional medium-sized 2 × 2 tunnels of cryptomelane. Todorokite was synthesized by the hydrothermal treatment of layered Na-birnessite in a concentrated Mg-containing solution according to a known method. In electrochemical studies, a promising discharge capacity of 108 mA h/g at C/2 and a good rate performance were observed in the potential range of 0.7 V–2.0 V. Structural and morphological analyses of the discharged and charged electrodes indicate that a reversible intercalation of zinc ions into the tunnel occurs during the discharge–charge process." @default.
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• W2003085274 date "2013-12-01" @default.
• W2003085274 modified "2023-10-02" @default.
• W2003085274 title "Todorokite-type MnO2 as a zinc-ion intercalating material" @default.
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• W2003085274 doi "https://doi.org/10.1016/j.electacta.2013.08.136" @default.
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