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• W2003097655 abstract "The effects of local structural disorder on excess electron transfer (EET) in DNA were investigated by evaluating photoinduced electron transfer in phenothiazine (PTZ)-modified oligodeoxynucleotides bearing single-base mismatches. Unexpectedly, more efficient electron transfer was observed for the mismatched duplexes than for the complementary DNA, suggesting that distraction of hydrogen bond interaction at the mismatch site enables electron injection or hopping beyond the mismatch sites. It was also anticipated that water accessibility of the mismatched nucleobases could affect EET because protonation of the electron-captured pyrimidine intermediates became competitive to EET, especially at the mismatch sites." @default.
• W2003097655 created "2016-06-24" @default.
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• W2003097655 date "2009-01-01" @default.
• W2003097655 modified "2023-10-17" @default.
• W2003097655 title "Pathways of excess electron transfer in phenothiazine-tethered DNA containing single-base mismatches" @default.
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• W2003097655 doi "https://doi.org/10.1039/b820311c" @default.
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