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- W2003104893 abstract "Abstract Boiling of the title compounds in ethereal solvents or cycloalkanes in the presence of a radical initiator leads to radical C(sp 3 )H functionalization, by which a sulfur atom is introduced into the ethereal solvents at the oxygenated carbon atom or into the cycloalkanes. Both acyclic and cyclic ethers, such as [18]crown‐6 and [D 8 ]THF, undergo the sulfur transfer. The reaction is useful for the synthesis of monothioacetals, thiols, and sulfides from simple starting materials." @default.
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- W2003104893 date "2007-11-27" @default.
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- W2003104893 title "O-AlkylS-3,3-Dimethyl-2-oxobutyl Dithiocarbonates as Versatile Sulfur-Transfer Agents in Radical C(sp3)H Functionalization" @default.
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- W2003104893 doi "https://doi.org/10.1002/asia.200700251" @default.
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