FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2003107392> ?p ?o ?g. }

• W2003107392 endingPage "362" @default.
• W2003107392 startingPage "347" @default.
• W2003107392 abstract "According to Sergio Trasatti, “A true theory of electrocatalysis will not be available until activity can be calculated a priori from some known properties of the materials.” Toward this goal, we developed intrinsic kinetic equations for the hydrogen oxidation reaction (HOR) and the oxygen reduction reaction (ORR) using as the kinetic parameters the free energies of adsorption and activation for elementary reactions. Rigorous derivation retained the intrinsic connection between the intermediates' adsorption isotherms and the kinetic equations, affording us an integrated approach for establishing the reaction mechanisms based upon various experimental and theoretical results. Using experimentally deduced free energy diagrams and activity-and-barriers plot for the ORR on Pt(111), we explained why the Tafel slope in the large overpotential region is double that in the small overpotential region. For carbon-supported Pt nanoparticles (Pt/C), the polarization curves measured with thin-film rotating disk electrodes also exhibit the double Tafel slope, albeit Pt(111) is several times more active than the Pt nanoparticles when the current is normalized by real surface area. An analytic method was presented for the polarization curves measured with H2 in proton exchange membrane fuel cells (PEMFCs). The fit to a typical iR-free polarization curve at 80 °C revealed that the change of the Tafel slope occurs at about 0.77 V that is the reversible potential for the transition between adsorbed O and OH on Pt/C. This is significant because it predicts that the Butler–Volmer equation can only fit the data above this potential, regardless the current density. We also predicted a decrease of the Tafel slope from 70 to 65 mV dec−1 at 80 °C with increasing oxygen partial pressure, which is consistent with the observation reported in literature." @default.
• W2003107392 created "2016-06-24" @default.
• W2003107392 creator A5012034576 @default.
• W2003107392 creator A5015761401 @default.
• W2003107392 creator A5048609660 @default.
• W2003107392 creator A5069928925 @default.
• W2003107392 creator A5080292559 @default.
• W2003107392 date "2009-01-01" @default.
• W2003107392 modified "2023-10-11" @default.
• W2003107392 title "Intrinsic kinetic equation for oxygenreduction reaction in acidic media: the double Tafel slope and fuelcell applications" @default.
• W2003107392 cites W1501673101 @default.
• W2003107392 cites W1975936460 @default.
• W2003107392 cites W1977425300 @default.
• W2003107392 cites W1994639390 @default.
• W2003107392 cites W2005027019 @default.
• W2003107392 cites W2009163408 @default.
• W2003107392 cites W2013467633 @default.
• W2003107392 cites W2022714449 @default.
• W2003107392 cites W2022854313 @default.
• W2003107392 cites W2029877130 @default.
• W2003107392 cites W2031965566 @default.
• W2003107392 cites W2032031209 @default.
• W2003107392 cites W2034379948 @default.
• W2003107392 cites W2038195588 @default.
• W2003107392 cites W2041769584 @default.
• W2003107392 cites W2050240027 @default.
• W2003107392 cites W2064503430 @default.
• W2003107392 cites W2067005286 @default.
• W2003107392 cites W2067415689 @default.
• W2003107392 cites W2074207002 @default.
• W2003107392 cites W2074646172 @default.
• W2003107392 cites W2085206439 @default.
• W2003107392 cites W2089398581 @default.
• W2003107392 cites W2128088324 @default.
• W2003107392 cites W2167035995 @default.
• W2003107392 cites W2171613439 @default.
• W2003107392 doi "https://doi.org/10.1039/b802218f" @default.
• W2003107392 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/19213326" @default.
• W2003107392 hasPublicationYear "2009" @default.
• W2003107392 type Work @default.
• W2003107392 sameAs 2003107392 @default.
• W2003107392 citedByCount "151" @default.
• W2003107392 countsByYear W20031073922012 @default.
• W2003107392 countsByYear W20031073922013 @default.
• W2003107392 countsByYear W20031073922014 @default.
• W2003107392 countsByYear W20031073922015 @default.
• W2003107392 countsByYear W20031073922016 @default.
• W2003107392 countsByYear W20031073922017 @default.
• W2003107392 countsByYear W20031073922018 @default.
• W2003107392 countsByYear W20031073922019 @default.
• W2003107392 countsByYear W20031073922020 @default.
• W2003107392 countsByYear W20031073922021 @default.
• W2003107392 countsByYear W20031073922022 @default.
• W2003107392 countsByYear W20031073922023 @default.
• W2003107392 crossrefType "journal-article" @default.
• W2003107392 hasAuthorship W2003107392A5012034576 @default.
• W2003107392 hasAuthorship W2003107392A5015761401 @default.
• W2003107392 hasAuthorship W2003107392A5048609660 @default.
• W2003107392 hasAuthorship W2003107392A5069928925 @default.
• W2003107392 hasAuthorship W2003107392A5080292559 @default.
• W2003107392 hasConcept C121332964 @default.
• W2003107392 hasConcept C132319479 @default.
• W2003107392 hasConcept C135502975 @default.
• W2003107392 hasConcept C135889238 @default.
• W2003107392 hasConcept C147789679 @default.
• W2003107392 hasConcept C148898269 @default.
• W2003107392 hasConcept C150394285 @default.
• W2003107392 hasConcept C161790260 @default.
• W2003107392 hasConcept C172404476 @default.
• W2003107392 hasConcept C17525397 @default.
• W2003107392 hasConcept C178790620 @default.
• W2003107392 hasConcept C179104552 @default.
• W2003107392 hasConcept C185592680 @default.
• W2003107392 hasConcept C186460083 @default.
• W2003107392 hasConcept C205049153 @default.
• W2003107392 hasConcept C33989665 @default.
• W2003107392 hasConcept C52859227 @default.
• W2003107392 hasConcept C62520636 @default.
• W2003107392 hasConcept C93391505 @default.
• W2003107392 hasConcept C95121573 @default.
• W2003107392 hasConcept C96606616 @default.
• W2003107392 hasConcept C97355855 @default.
• W2003107392 hasConceptScore W2003107392C121332964 @default.
• W2003107392 hasConceptScore W2003107392C132319479 @default.
• W2003107392 hasConceptScore W2003107392C135502975 @default.
• W2003107392 hasConceptScore W2003107392C135889238 @default.
• W2003107392 hasConceptScore W2003107392C147789679 @default.
• W2003107392 hasConceptScore W2003107392C148898269 @default.
• W2003107392 hasConceptScore W2003107392C150394285 @default.
• W2003107392 hasConceptScore W2003107392C161790260 @default.
• W2003107392 hasConceptScore W2003107392C172404476 @default.
• W2003107392 hasConceptScore W2003107392C17525397 @default.
• W2003107392 hasConceptScore W2003107392C178790620 @default.
• W2003107392 hasConceptScore W2003107392C179104552 @default.
• W2003107392 hasConceptScore W2003107392C185592680 @default.
• W2003107392 hasConceptScore W2003107392C186460083 @default.
• W2003107392 hasConceptScore W2003107392C205049153 @default.
• W2003107392 hasConceptScore W2003107392C33989665 @default.

• next