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- W2003108152 abstract "Quantitative measurements of the variation in nitroxide free radical concentration on exposure to ultraviolet (uv) light are reported for a melamine crosslinked acrylic copolymer film doped with a hindered amine light stabiliser (bis (2,2,6,6-tetramethyl-4-piperidinyl) sebacate) as a function of hindered amine concentration, light intensity and humidity. The concentration of nitroxide is found to rise to a maximum and then slowly decrease. The following parameters can be derived from the nitroxide data: the net rate of formation of nitroxide during the early stages of exposure, the maximum nitroxide concentration, the time to maximum and the net decay rate at long exposure times. The observed variations in these parameters with exposure conditions are discussed. It is found that the humidity of the exposure greatly influences the degradation and stabilisation chemistry of acrylic-melamine coatings." @default.
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- W2003108152 date "1986-01-01" @default.
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- W2003108152 title "Photo-stabilisation and photo-degradation in organic coatings containing a hindered amine light stabiliser. Part I—ESR measurements of nitroxide concentration" @default.
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- W2003108152 doi "https://doi.org/10.1016/0141-3910(86)90021-2" @default.
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