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• W2003111314 abstract "Films with a composition PbZr0.53Ti0.47O3 were prepared on different platinum bottom electrodes using a spin-coating process followed by metalorganic decomposition. The film morphology and structure were characterized by scanning electron microscopy and x-ray diffraction analysis. The morphology was strongly influenced by the heat cycle used to form the PbZr0.53Ti0.47O3 layer. Fast heating and high-fire temperatures produced smooth films, while slow heating and low-fire temperatures gave films having a rosette perovskite phase and an inter-rosette second phase. The films were characterized electrically by measuring hysteresis loops and capacitance and conductance versus bias voltage and by pulse-switching measurements. The dependence of the switched and nonswitched polarization on the number of switching cycles (i.e., the fatigue behavior) is found to be much better for fast-heated than for slowly heated films. Switching lifetimes exceeding 1011 cycles were measured. The type of platinum bottom electrode used was found to have a large influence on the ferroelectric properties of the lead zirconate titanate films." @default.
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• W2003111314 date "1991-08-15" @default.
• W2003111314 modified "2023-10-17" @default.
• W2003111314 title "Preparation and ferroelectric properties of PbZr0.53Ti0.47O3 thin films by spin coating and metalorganic decomposition" @default.
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• W2003111314 doi "https://doi.org/10.1063/1.349422" @default.
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