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- W2003118906 abstract "Bis(pentamethylcyclopentadienyl)calcium, (C5Me5)2Ca, can be made by the reaction of Ca[N(SiMe3)2]2 with C5Me5H in toluene. It undergoes cyclopentadienyl ring metathesis with tris(cyclopentadienyl)lanthanide complexes, Cp3Ln (Ln = La, Nd, Sm) in toluene to generate the mixed ring complexes (C5Me5)2LnCp. The X-ray crystal structure of (C5Me5)2NdCp shows that the complex is a sterically crowded monomer with η5-C5Me5 and Cp rings. The average NdC distances for both the C5Me5 and Cp rings are 2.76–2.79 Å." @default.
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- W2003118906 date "1995-01-01" @default.
- W2003118906 modified "2023-09-25" @default.
- W2003118906 title "Cyclopentadienyl ring metathesis with bis(pentamethylcyclopentadienyl)calcium as a route to mixed ring organolanthanide complexes; the crystal structure of (C5Me5)2Nd(C5H5)" @default.
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- W2003118906 doi "https://doi.org/10.1016/0277-5387(94)00316-7" @default.
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