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- W2003119005 abstract "Three complexes [Mn(pzda)(H2O)2]n (1), [Mn(pzda)(bpy)]n (2) and [Mn(pzda)(phen)(H2O)2] (3) (H2pzda = pyrazine-2,6-dicarboxylic acid, bpy = 2,2′-bipyridine, phen = 1,10-phenanthroline) were synthesized by the hydro(solvo)thermal reaction and characterized by single crystal X-ray diffraction, elemental analysis, IR spectrum. Complex 1 is a 2D bilayer structure in which each Mn(II) ion is coordinated to two oxygen atoms and two nitrogen atoms from three pzda ligands and two oxygen atoms of two water molecules. Complex 2 is a 3D metal-organic framework structure. Mn(II) is seven-coordinated: four oxygen atoms and one nitrogen atom from three pzda ligands and other two nitrogen atoms from one bpy molecule, displaying a distorted pentagonal bipyramid geometry. While complex 3 is a mononuclear structure in which Mn(II) ion is seven-coordinated to one pzda, one phen, and two water molecules. The complex is connected into a 3D supramolecular network via hydrogen-bonding and π–π stacking interactions. In each of complexes 1–3, pzda ligands adopt different coordination mode." @default.
- W2003119005 created "2016-06-24" @default.
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- W2003119005 date "2006-10-01" @default.
- W2003119005 modified "2023-09-27" @default.
- W2003119005 title "Effect of terminal ligands on assembly of manganese(II) complexes with pyrazine-2,6-dicarboxylic acid" @default.
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- W2003119005 doi "https://doi.org/10.1016/j.molstruc.2006.03.084" @default.
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