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- W2003125341 abstract "Compounds [NH3(CH2)4NH3]Cu3(hedp)2·2H2O (1) and [NH3(CH2)3NH3]Cu3(hedp)2·3.5H2O (2), where hedp represents 1-hydroxyethylidenediphosphonate, exhibit two-dimensional structures closely related to each other. The anionic layers with composition {Cu3(hedp)2}n2n- contain four- and eight-membered rings assembled from vertex-sharing {CuO4} units and {CPO3} tetrahedra. The protonated diamines and lattice water fill the interlayer spaces. Crystal data for 2: space group P1, a = 8.0315(4), b = 11.3713(6), c = 13.3117(7) A, α = 97.122(1), β = 103.187(1), γ = 108.668(1)°, V = 1095.5(1) A3, Z = 2. Magnetic properties of the two compounds have been investigated. Both show typical metamagnetic behaviors at low temperature. The critical field at which the antiferromagnetic ground-state switches to a ferrimagnetic state is ∼48 Oe for 1 and 185 Oe for 2 at about 2 K." @default.
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- W2003125341 date "2002-06-13" @default.
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- W2003125341 title "Metamagnetic Copper(II) Diphosphonates with Layered Structures" @default.
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- W2003125341 doi "https://doi.org/10.1021/cm020204+" @default.
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