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• W2003132842 abstract "The lattice vibrations of the AIIBIII2CVI4 semiconductors with defect-chalcopyrite structure are treated in a simplified version of the Keating model considering only interaction with nearest neighbours and assuming that all anions occupy their ideal lattice sites. It is found that in this model the frequencies of the nonpolar and polar modes with highest energy are determined by the properties of the BIII–CVI sublattice alone. The frequencies of all the other optical modes depend not only on the AII–CVI and BIII–CVI interactions but are also influenced by the presence of the ordered array of vacancies. The results obtained are compared with previous model considerations. Die Gitterschwingungen der AIIBIII2CVI4-Halbleiter mit Defekt-Chalkopyrit-Struktur werden in einer vereinfachten Version des Keating-Modells behandelt, wobei nur die Wechselwirkungen zwischen nächsten Nachbarn berücksichtigt werden und vorausgesetzt wird, daß alle Anionen ihre idealen Gitterplätze besetzen. Es wird gefunden, daß in diesem Modell die Frequenzen der nichtpolaren und polaren Moden mit der höchsten Energie allein durch die Eigenschaften des BIII–CVI–Untergitters bestimmt werden. Die Frequenzen aller anderen optischen Moden hängen nicht nur von den AII–CVI–und BIII–CVI-Wechselwirkungen ab, sondern werden auch durch das Vorhandensein des geordneten Vakanzensystems beeinflußt. Die erhaltenen Ergebnisse werden mit früheren Modellbetrachtungen verglichen." @default.
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• W2003132842 creator A5008230822 @default.
• W2003132842 date "1991-01-01" @default.
• W2003132842 modified "2023-09-27" @default.
• W2003132842 title "Lattice Vibrations and Interatomic Forces in AIIB2IIIC4VI Defect-Chalcopyrite Compounds (I) Keating Model Considerations" @default.
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• W2003132842 doi "https://doi.org/10.1002/crat.2170260807" @default.
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