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- W2003151711 abstract "Abstract N - n -Propyl-2-pyridylmethanimine, 1 , N - n -octyl-2-pyridylmethanimine, 2 , N - n -lauryl-2-pyridylmethanimine, 3 , and N - n -octadecyl-2-pyridylmethanimine, 4 have been used in conjunction with copper(II) bromide and azo initiators for the reverse atom transfer radical polymerisation of a range of methacrylates. AIBN to Cu II Br 2 ratios of 0.5:1, 0.75:1 and 1:1 give PMMA with M n 11 500 g mol −1 (PDi = 1.24) (at 22% conversion), 12 500 g mol −1 (PDi = 1.06) (at 83% conversion) and 10 900 g mol −1 (PDi = 1.11) (at 84% conversion), respectively. A Cu II Br 2 complex is demonstrated to be needed at the start of the reaction for good control over molecular weight and polydispersity as reactions using Cu(I)Br as catalyst yielded PMMA of M n 31 000 g mol −1 (PDi = 2.90), reactions with no copper yield PMMA of M n 33 000 g mol −1 (PDi = 2.95). The RATRP of styrene was carried out using Cu II Br 2 as catalyst. AIBN to Cu II Br 2 ratio of 0.5:1, 0.75:1 and 1:1 gave PS with M n = 12 400 g mol −1 (PDi = 1.27) at low conversion, M n = 15 500 g mol −1 (PDi = 1.11) and 12 400 g mol −1 (PDi = 1.38), respectively at ∼85% conversion. A series of block copolymers of MMA with BMA, BzMA and DMEAMA (15 600 g mol −1 (PDi = 1.18), 13 300 g mol −1 (PDi = 1.14) 15 300 g mol −1 (PDi) = 1.16), using a PMMA macroinitiator were prepared. Emulsion polymerisation of MMA using [initiator]:[Cu (II) Br 2 ] ratio = 0.5:1 with Brij surfactant gave a linear increase of M n with respect to conversion, final M n = 112 800 g mol −1 (PDi = 1.42). Further reactions were carried out with [initiator]:[Cu (II) Br 2 ] ratio = 0.75:1 and 1:1. Both giving PMMA with M n ∼ 32 000 g mol −1 (PDi ∼ 2.4). These reactions exhibit no control, this is because the azo initiator is present in excess and all of the monomer is consumed by a free radical polymerisation as opposed to a controlled reaction. Particle size analysis (DLS) showed the particle size between 160 and170 nm in all cases." @default.
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- W2003151711 date "2006-01-01" @default.
- W2003151711 modified "2023-09-25" @default.
- W2003151711 title "Reverse atom transfer radical polymerisation (RATRP) of methacrylates using copper(I)/pyridinimine catalysts in conjunction with AIBN" @default.
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- W2003151711 doi "https://doi.org/10.1016/j.eurpolymj.2005.08.011" @default.
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