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- W2003155807 abstract "Abstract Flash vacuum pyrolysis (FVP) of the N -(adamantan-1-yl)hexafluorothioacetone S -imide ( 1b ) yielded an isomeric compound 4 without extrusion of the sulfur atom. On the other hand, thermolysis of the same S -imide in CDCl 3 -solution afforded dithiazolidine 5 as the main product. Thermal cleavage of 1b leading to in situ formation of hexafluorothioacetone is the primary reaction in solution. [3+2]-Cycloadditions of 1b with strained trans -cyclooctene and dimethyl norbornenedicarboxylate occurred smoothly at ambient temperature with no decomposition and/or isomerisation. Reactions with less reactive cycloaliphatic thioketones 8a - b were carried out at elevated temperature and gave products of multi-step processes. Isomerisation of 1b which competes with the cleavage to hexafluorothioacetone, is postulated in order to explain the structures of the isolated products." @default.
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- W2003155807 date "2000-06-01" @default.
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- W2003155807 title "Ambiguous Reactivity of a Fluorinated Thiocarbonyl S -Imide; Unprecedented Rearrangement under FVP Conditions" @default.
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- W2003155807 doi "https://doi.org/10.1016/s0040-4020(00)00348-3" @default.
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