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- W2003156727 abstract "The ligand groups PPh2, PEt2, and AsPh2 have been bonded to macroreticular polystyrene and treated with [IrCl(C8H14)2]2 and Et3SiH. The resulting materials were used to catalyse the reaction between ethanol and polymethylhydrogendisiloxane, Me3SiO[Si(Me)(H)O]nSiMe3 (n = ca. 50). The arsine system showed very little useful activity. The Et2P system had good activity initially, rather less on recovery and reuse in five more reactions, and then suddenly decreased in activity. For PPh2, the catalyst showed a steady decline in two dozen reaction cycles. In each case, the separated liquid products showed catalytic activity, demonstrating that leaching of the metal from the support was occurring. The addition of the metal-free supported ligand inhibited the leaching, and stabilised the activity over at least a dozen cycles." @default.
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- W2003156727 date "1984-03-01" @default.
- W2003156727 modified "2023-09-26" @default.
- W2003156727 title "Polymer-supported catalysts for the reaction of ethanol with polymethylhydrogendisiloxane" @default.
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- W2003156727 doi "https://doi.org/10.1016/s0022-328x(00)99177-0" @default.
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