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- W2003160918 abstract "The synthesis of gmelanone 2 by a pinacol-type rearrangement of arboreol 1 supports its biogenesis and confirms its relative and absolute configuration. The further transformation of gmelanone oxime 12 into the dihydropyranone oxime 13 supports the intermediacy of gmelanone like intermediates in the rearrangements of furofuran lignans to pyran derivatives. In contrast, acid-catalysed rearrangement of wodeshiol 7 affords the dihydropyranone 8." @default.
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- W2003160918 date "2005-09-01" @default.
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- W2003160918 title "Transformations of lignans. Part 10: Acid-catalysed rearrangements of arboreol and wodeshiol and conversion of gmelanone oxime into a dihydropyranone derivative" @default.
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- W2003160918 doi "https://doi.org/10.1016/j.tet.2005.06.106" @default.
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