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- W2003168918 abstract "We describe a reverse perturbation effect of a cyclopropyl group on facial selectivities in two bicyclic systems, bicyclo[2.2.2]octane and norbornane (bicyclo[2.2.1]heptane). In terms of facial selective behavior, the cyclopropyl group embedded in the bicyclo[2.2.2]octene seems to be equivalent to a substitution of an electron-withdrawing group, although this is in sharp contrast to the conventional understanding of this group as strongly electron-donating. © 1997 Elsevier Science Ltd." @default.
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- W2003168918 date "1997-09-01" @default.
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- W2003168918 title "A Cyclopropyl Group Shows Reverse Facial Selectivity Depending on the Bicyclic Ring System" @default.
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- W2003168918 doi "https://doi.org/10.1016/s0040-4039(97)01567-0" @default.
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