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- W2003177766 abstract "The structural phase transitions in LiKSO4 have been examined by EPR, at X band, using a paramagnetic SO4- probe. The orientation of the SO4- probe ion is modified with respect to that of the parent SO42- ion. The authors show that this modified orientation and its temperature-dependent motion has misled earlier workers into suggesting an unusual sequence of commensurate-incommensurate transitions in LiKSO4. Their measurements also support the occurrence of another transition in this compound at 130 K, as predicted by neutron diffraction work. This transition appears to trigger an anti-ferro-distortion resulting in the rotation of SO4- by +or-10 degrees about the c axis; all of the sulphates remain chemically equivalent. LiKSO4 exists below 130 K as a mixed-phase compound down to 77 K." @default.
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- W2003177766 date "1987-03-30" @default.
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- W2003177766 title "Absence of unusual sequence of commensurate-incommensurate phase transitions in LiKSO4: an EPR study using an SO4-probe" @default.
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- W2003177766 doi "https://doi.org/10.1088/0022-3719/20/9/008" @default.
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