FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2003178210> ?p ?o ?g. }

• W2003178210 endingPage "185" @default.
• W2003178210 startingPage "177" @default.
• W2003178210 abstract "Abstract In the framework of structure/activity correlation studies the plant growth hormone auxin and its natural analogue 4-Cl-IAA, as well as their synthetic congeners, were studied by FTIR spectroscopy. The analysis was focused on the NH and CO stretching vibrations which can be the most sensitive probes of intra- and intermolecular interactions, particularly to hydrogen bonds. However, it emerged that vC = O vibrations of both monomer and dimer are not affected by substitution. The aliphatic CH2 group acts as an insulator between the conjugated π-system of indole and the carboxylic group, thus prohibiting a direct effect on the vibration CO. On the contrary, the stretching vibrations NH are influenced by halogenation and hydrogen bonding. The experimental data are in good agreement with the results of quantum chemical ab initio calculations of NH vibrations for IAA and several chlorine substituted IAAs. However, a simple correlation between substitution and spectral properties of indole NH cannot be found. The measurements were performed in the solid state (KBr pellets) and in polar (diethylether) and nonpolar (CDCI3) solutions. From the measurements in diethylether, it follows that in dilute solution IAA and derivatives are predominantly present as monomer, whereas in CDCl3 the equilibrium is in favour of the dimer form. In aqueous solution at the concentrations used in growth experiments solvated monomer will be the active component. Bioactivity of auxin and analogues with their NH stretching frequency shifts cannot be correlated in a simple way." @default.
• W2003178210 created "2016-06-24" @default.
• W2003178210 creator A5021273943 @default.
• W2003178210 creator A5049811250 @default.
• W2003178210 creator A5061088267 @default.
• W2003178210 creator A5064683587 @default.
• W2003178210 creator A5083431043 @default.
• W2003178210 creator A5088648597 @default.
• W2003178210 date "1996-09-01" @default.
• W2003178210 modified "2023-10-13" @default.
• W2003178210 title "FTIR spectroscopic study of the phytohormone auxin (Indol-3-ylacetic Acid, IAA) and its n-alkylated and monohalogenated derivatives" @default.
• W2003178210 cites W1497908709 @default.
• W2003178210 cites W1543093790 @default.
• W2003178210 cites W1650728208 @default.
• W2003178210 cites W1968104552 @default.
• W2003178210 cites W1970388511 @default.
• W2003178210 cites W1977643268 @default.
• W2003178210 cites W1978104625 @default.
• W2003178210 cites W1978633893 @default.
• W2003178210 cites W1994968304 @default.
• W2003178210 cites W2003999744 @default.
• W2003178210 cites W2004009293 @default.
• W2003178210 cites W2011079470 @default.
• W2003178210 cites W2022503188 @default.
• W2003178210 cites W2022950330 @default.
• W2003178210 cites W2024532226 @default.
• W2003178210 cites W2033234549 @default.
• W2003178210 cites W2046412723 @default.
• W2003178210 cites W2047506966 @default.
• W2003178210 cites W2051268989 @default.
• W2003178210 cites W2067461848 @default.
• W2003178210 cites W2071680783 @default.
• W2003178210 cites W2073322297 @default.
• W2003178210 cites W2084136082 @default.
• W2003178210 cites W2093827204 @default.
• W2003178210 cites W2094642658 @default.
• W2003178210 cites W2094754465 @default.
• W2003178210 cites W2142257645 @default.
• W2003178210 cites W2145813865 @default.
• W2003178210 cites W2332449045 @default.
• W2003178210 cites W4247934600 @default.
• W2003178210 cites W53643417 @default.
• W2003178210 doi "https://doi.org/10.1016/0022-2860(96)09244-7" @default.
• W2003178210 hasPublicationYear "1996" @default.
• W2003178210 type Work @default.
• W2003178210 sameAs 2003178210 @default.
• W2003178210 citedByCount "8" @default.
• W2003178210 countsByYear W20031782102022 @default.
• W2003178210 countsByYear W20031782102023 @default.
• W2003178210 crossrefType "journal-article" @default.
• W2003178210 hasAuthorship W2003178210A5021273943 @default.
• W2003178210 hasAuthorship W2003178210A5049811250 @default.
• W2003178210 hasAuthorship W2003178210A5061088267 @default.
• W2003178210 hasAuthorship W2003178210A5064683587 @default.
• W2003178210 hasAuthorship W2003178210A5083431043 @default.
• W2003178210 hasAuthorship W2003178210A5088648597 @default.
• W2003178210 hasConcept C104317684 @default.
• W2003178210 hasConcept C161790260 @default.
• W2003178210 hasConcept C164361826 @default.
• W2003178210 hasConcept C178790620 @default.
• W2003178210 hasConcept C185592680 @default.
• W2003178210 hasConcept C207778908 @default.
• W2003178210 hasConcept C55493867 @default.
• W2003178210 hasConcept C71240020 @default.
• W2003178210 hasConceptScore W2003178210C104317684 @default.
• W2003178210 hasConceptScore W2003178210C161790260 @default.
• W2003178210 hasConceptScore W2003178210C164361826 @default.
• W2003178210 hasConceptScore W2003178210C178790620 @default.
• W2003178210 hasConceptScore W2003178210C185592680 @default.
• W2003178210 hasConceptScore W2003178210C207778908 @default.
• W2003178210 hasConceptScore W2003178210C55493867 @default.
• W2003178210 hasConceptScore W2003178210C71240020 @default.
• W2003178210 hasIssue "3" @default.
• W2003178210 hasLocation W20031782101 @default.
• W2003178210 hasOpenAccess W2003178210 @default.
• W2003178210 hasPrimaryLocation W20031782101 @default.
• W2003178210 hasRelatedWork W1531601525 @default.
• W2003178210 hasRelatedWork W2384464875 @default.
• W2003178210 hasRelatedWork W2569169118 @default.
• W2003178210 hasRelatedWork W2606230654 @default.
• W2003178210 hasRelatedWork W2607424097 @default.
• W2003178210 hasRelatedWork W2748952813 @default.
• W2003178210 hasRelatedWork W2899084033 @default.
• W2003178210 hasRelatedWork W2948807893 @default.
• W2003178210 hasRelatedWork W4387497383 @default.
• W2003178210 hasRelatedWork W2778153218 @default.
• W2003178210 hasVolume "382" @default.
• W2003178210 isParatext "false" @default.
• W2003178210 isRetracted "false" @default.
• W2003178210 magId "2003178210" @default.
• W2003178210 workType "article" @default.