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Matches in SemOpenAlex for { <https://semopenalex.org/work/W2003180722> ?p ?o ?g. }

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• W2003180722 abstract "The [Pd(SIPr)(PCy3)] complex efficiently promotes a tandem process involving dehydrogenation of formic acid and hydrogenation of C–C multiple bonds using H2 formed in situ. The isolation of a key catalytic hydridoformatopalladium species, [Pd{OC(O)H}(H)(IPr)(PCy3)], is reported. The complex plays a key role in the Pd(0)-mediated formation of hydrogen from formic acid. Mechanistic and computational studies delineate the operational role of the palladium complex in this efficient tandem sequence." @default.
• W2003180722 created "2016-06-24" @default.
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• W2003180722 date "2013-01-14" @default.
• W2003180722 modified "2023-10-11" @default.
• W2003180722 title "The Isolation of [Pd{OC(O)H}(H)(NHC)(PR₃)] (NHC = N-Heterocyclic Carbene) and Its Role in Alkene and Alkyne Reductions Using Formic Acid" @default.
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• W2003180722 doi "https://doi.org/10.1021/ja311087c" @default.
• W2003180722 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23316939" @default.
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