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- W2003183876 abstract "Isopropylidene-protected (S)-4-O-(methylsulfonyl)butane-1,2,4-triol was used for alkylation of 5-[(pyren-3-yl)methylidene]hydantoin to give the N3-monoalkylated product 4 in 29% yield together with a dialkylated product 5 in 12% yield. After deprotection, compound 4 was transformed into a dimethoxytrityl (DMT)-protected phosphoramidite building block 9 for standard DNA synthesis. When inserted as a bulge in the triplex-forming oligomer, compound 6 stabilizes a DNA triplex, whereas the corresponding DNA/DNA and DNA/RNA duplexes are slightly destabilized. For the triplex, fluorescence enhancement was observed at 500 nm." @default.
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- W2003183876 date "2005-12-01" @default.
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- W2003183876 title "Intercalating Nucleic Acids with Insertion of 5-[(Pyren-1-yl)methylidene]hydantoin-Substituted Butane-1,2-diol" @default.
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- W2003183876 doi "https://doi.org/10.1002/hlca.200590253" @default.
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