FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2003184536> ?p ?o ?g. }

• W2003184536 endingPage "706" @default.
• W2003184536 startingPage "696" @default.
• W2003184536 abstract "We present a systematic experimental investigation on the infrared (IR) vibrational absorption spectroscopy of the n-Si/acetonitrile interface utilizing the attenuated total internal-reflection geometry in the near-infrared (1.1–5 μm) spectral region. The IR absorption of the interface has been isolated selectively by electromodulation, and studied as a function of modulation potential. The electrochemical behavior of the interface has been checked by current/voltage and impedance measurements. The IR spectra are composed of a broad background and various sharp vibrational peaks. The background can be analyzed as the sum of two contributions: (i) absorption by surface states at shorter wavelengths (&lt;2 μm), (ii) free-carrier absorption at longer wavelengths. The free-carrier contribution is itself composed of a Drude-like component (proportional to λ3/2) and an interband component. The vibrational peaks can be ascribed to the C≡N, C–H, Si–H, and (Si–)O–H chemical bonds. The shapes and magnitudes of the C≡N and C–H peaks can be quantitatively understood in terms of displaced ions and acetonitrile molecules near the surface upon the electrode potential modulation. The shape of the C≡N peak also gives an indication of a weak interaction of the acetonitrile molecules with the electrode surface. The Si–H and (Si–)O–H peaks can be interpreted in terms of Stark effect modulation of the infrared absorption of these species. The shape of the O–H peak indicates the presence of nonequivalent sites at the interface. Upon the electrode aging and oxidation the magnitude of the Si–H peak decreases and the (Si–)O–H peak increases and correspondingly the surface-state density increases which provides a direct in situ physicochemical information regarding the slow oxidation of the electrode surface." @default.
• W2003184536 created "2016-06-24" @default.
• W2003184536 creator A5021558058 @default.
• W2003184536 creator A5035725929 @default.
• W2003184536 creator A5077202582 @default.
• W2003184536 date "1986-07-15" @default.
• W2003184536 modified "2023-10-10" @default.
• W2003184536 title "<i>I</i> <i>n</i> <i>s</i> <i>i</i> <i>t</i> <i>u</i> characterization of the <i>n</i>-Si/acetonitrile interface by electromodulated infrared internal-reflection spectroscopy" @default.
• W2003184536 cites W1559284604 @default.
• W2003184536 cites W157972092 @default.
• W2003184536 cites W1968543977 @default.
• W2003184536 cites W1971127329 @default.
• W2003184536 cites W1973955035 @default.
• W2003184536 cites W1975938445 @default.
• W2003184536 cites W1977744295 @default.
• W2003184536 cites W1985918070 @default.
• W2003184536 cites W1989255294 @default.
• W2003184536 cites W1993313805 @default.
• W2003184536 cites W1995062895 @default.
• W2003184536 cites W2003856270 @default.
• W2003184536 cites W2016038073 @default.
• W2003184536 cites W2022779595 @default.
• W2003184536 cites W2025509108 @default.
• W2003184536 cites W2032789518 @default.
• W2003184536 cites W2034759196 @default.
• W2003184536 cites W2034792287 @default.
• W2003184536 cites W2035378369 @default.
• W2003184536 cites W2035408704 @default.
• W2003184536 cites W2041162956 @default.
• W2003184536 cites W2047058195 @default.
• W2003184536 cites W2053015972 @default.
• W2003184536 cites W2053782806 @default.
• W2003184536 cites W2055176535 @default.
• W2003184536 cites W2058930597 @default.
• W2003184536 cites W2062945604 @default.
• W2003184536 cites W2072165727 @default.
• W2003184536 cites W2074852576 @default.
• W2003184536 cites W2082864843 @default.
• W2003184536 cites W2087158103 @default.
• W2003184536 cites W2087934132 @default.
• W2003184536 cites W2089958839 @default.
• W2003184536 cites W2093290670 @default.
• W2003184536 cites W2094093348 @default.
• W2003184536 cites W2095242917 @default.
• W2003184536 cites W2100024073 @default.
• W2003184536 cites W2108717274 @default.
• W2003184536 cites W2950565120 @default.
• W2003184536 doi "https://doi.org/10.1063/1.337417" @default.
• W2003184536 hasPublicationYear "1986" @default.
• W2003184536 type Work @default.
• W2003184536 sameAs 2003184536 @default.
• W2003184536 citedByCount "35" @default.
• W2003184536 countsByYear W20031845362016 @default.
• W2003184536 countsByYear W20031845362018 @default.
• W2003184536 countsByYear W20031845362019 @default.
• W2003184536 countsByYear W20031845362021 @default.
• W2003184536 countsByYear W20031845362022 @default.
• W2003184536 countsByYear W20031845362023 @default.
• W2003184536 crossrefType "journal-article" @default.
• W2003184536 hasAuthorship W2003184536A5021558058 @default.
• W2003184536 hasAuthorship W2003184536A5035725929 @default.
• W2003184536 hasAuthorship W2003184536A5077202582 @default.
• W2003184536 hasConcept C113196181 @default.
• W2003184536 hasConcept C119824511 @default.
• W2003184536 hasConcept C120665830 @default.
• W2003184536 hasConcept C121332964 @default.
• W2003184536 hasConcept C125287762 @default.
• W2003184536 hasConcept C147789679 @default.
• W2003184536 hasConcept C153642686 @default.
• W2003184536 hasConcept C158355884 @default.
• W2003184536 hasConcept C159985019 @default.
• W2003184536 hasConcept C17525397 @default.
• W2003184536 hasConcept C178790620 @default.
• W2003184536 hasConcept C185592680 @default.
• W2003184536 hasConcept C18787249 @default.
• W2003184536 hasConcept C192562407 @default.
• W2003184536 hasConcept C24123453 @default.
• W2003184536 hasConcept C2777463227 @default.
• W2003184536 hasConcept C32909587 @default.
• W2003184536 hasConcept C43617362 @default.
• W2003184536 hasConcept C52859227 @default.
• W2003184536 hasConceptScore W2003184536C113196181 @default.
• W2003184536 hasConceptScore W2003184536C119824511 @default.
• W2003184536 hasConceptScore W2003184536C120665830 @default.
• W2003184536 hasConceptScore W2003184536C121332964 @default.
• W2003184536 hasConceptScore W2003184536C125287762 @default.
• W2003184536 hasConceptScore W2003184536C147789679 @default.
• W2003184536 hasConceptScore W2003184536C153642686 @default.
• W2003184536 hasConceptScore W2003184536C158355884 @default.
• W2003184536 hasConceptScore W2003184536C159985019 @default.
• W2003184536 hasConceptScore W2003184536C17525397 @default.
• W2003184536 hasConceptScore W2003184536C178790620 @default.
• W2003184536 hasConceptScore W2003184536C185592680 @default.
• W2003184536 hasConceptScore W2003184536C18787249 @default.
• W2003184536 hasConceptScore W2003184536C192562407 @default.
• W2003184536 hasConceptScore W2003184536C24123453 @default.
• W2003184536 hasConceptScore W2003184536C2777463227 @default.
• W2003184536 hasConceptScore W2003184536C32909587 @default.

• next