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• W2003189262 abstract "The wet air oxidation of phenol over a commercial active carbon catalyst has been studied in laboratory-scale and pilot-plant fixed-bed reactors at mild temperatures and oxygen partial pressures of 120−160 °C and 0.05−0.2 MPa, respectively. The performances of the fixed-bed reactors have been assessed and compared to each other for both up- and downflow operation mode. Depending on the flow mode and reactor scale, distinct phenol destruction rates have been observed in the experiments. A series of batch experiments are carried out to obtain phenol removal kinetics, which are subsequently implemented in the modeling of the pilot-plant fixed-bed reactor. A one-dimensional, nonisothermal piston dispersion model is developed to describe in detail the interplay of reaction kinetics, gas−liquid hydrodynamics, and heat and mass transfer in both flow directions. The model predicts reasonably well the experimental data, thus allowing for a thorough explanation of the observed pilot-plant reactor performance." @default.
• W2003189262 created "2016-06-24" @default.
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• W2003189262 date "2005-06-08" @default.
• W2003189262 modified "2023-10-18" @default.
• W2003189262 title "Scale-up and Modeling of Fixed-Bed Reactors for Catalytic Phenol Oxidation over Adsorptive Active Carbon" @default.
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• W2003189262 doi "https://doi.org/10.1021/ie050242d" @default.
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