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- W2003192810 abstract "The microwave spectra of CF3PH2, CF3PHD, and CF3PD2 have been observed and analyzed. The barrier to internal rotation is 2360 ± 80 cal/mole, approximately 400 cal/mole higher than the barrier in CH3PH2. The dipole‐moment components are μa = 1.77 ± 0.01 D, μc = 0.74 ± 0.03 D, and μtotal = 1.92 ± 0.02 D. The structural parameters are rC−P = 1.900 ± 0.006 Å, rP−H = 1.43 ± 0.08 Å, ∠FCF = 108.0 ± 0.4°, ∠CPH 91.9 ± 1.9°, and ∠HPH = 96.7 ± 1.8°. Compared with CH3PH2, the C‐P bond is significantly longer, ∠CPH is smaller, and ∠HPH is larger." @default.
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- W2003192810 date "1968-01-15" @default.
- W2003192810 modified "2023-10-17" @default.
- W2003192810 title "Microwave Spectrum, Barrier to Internal Rotation, Dipole Moment, and Structure of Trifluoromethylphosphine" @default.
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- W2003192810 doi "https://doi.org/10.1063/1.1668716" @default.
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