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- W2003202014 abstract "Abstract The title compound 1 was synthesized via addition of dichlorocarbene to dimethyl trars ‐3‐hexenedioate ( 5 ), using o ‐nitrophenylselenic acid‐elimination to form the double bonds. Reaction of dichlorocyclopropane 8 with ozone on silica gel furnished the monoketone 10 ; no diketone 11 could be isolated upon further exposure of 10 to O 3 /SiO 2 . When the bis( p ‐toluenesulfonate) 13b was treated with t ‐BuOK, 16 was obtained in low yield as the only isolable product. It is believed to arise from Cope ‐rearrangement of an intermediate cis ‐divinylcyclopropane 14 to cycloheptadiene 15 , which undergoes a subsequent allylic rearrangement to 16 ." @default.
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- W2003202014 date "1982-06-16" @default.
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- W2003202014 title "Note on the Synthesis of 1, 1-Dichloro-2, 3-divinylcyclopropane and Other Functionalized Dichlorocyclopropanes" @default.
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- W2003202014 doi "https://doi.org/10.1002/hlca.19820650407" @default.
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