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- W2003205005 abstract "The structural and magnetic phase transitions in the series of compounds (CnH2n + 1 NH3)2MnCl4 with n = 5,7, and 9 are studied by means of X-ray diffraction, differential scanning calorimetry, and magnetic susceptibility experiments. Like the previously studied first members of the series (n = 1 to 3), these perovskite-like layer compounds undergo at low temperature an antiferromagnetic transition with weak ferromagnetic moment due to spin canting. In the paramagnetic domain, the magnetic susceptibility is sensitive to a first-order phase transition which could be due to the freezing of alkyl ammonium groups. Les transitions magnétiques et structurales dans la série de composés (CnH2n + 1 NH3)2MnCl4 avec n = 5, 7, et 9 sont étudiées par diffraction des rayons X, calorimétrie et mesures de susceptibilité magnétique. Comme les premiers membres de la série précedemment étudiés (n = 1 à 3), ces composés lamellaires de type pérovskite présentent, à basse température, une transition antiferromagnétique avec un ferromagnétisme faible résultant d'un “spin-canting”. Dans le domaine paramagnétique, la susceptibilité est sensible à une transition structurale du premier ordre qui est vraisemblablement due au gel des groupements alkyl-ammonium." @default.
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- W2003205005 title "Structural and magnetic phase transitions in bis-(alkyl ammonium) manganese tetrachlorides (CnH2n+1NH3)2MnCl4 withIn = 5, 7, and 9" @default.
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- W2003205005 doi "https://doi.org/10.1002/pssa.2211490221" @default.
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