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- W2003206488 abstract "Abstract Three manganese(III) complexes with the ligand bzacen2- [bzacen2-= N,N′-ethylenebis (l−phenyl-3-imino-l-butanonato)], Mn(bzacen) (pyridine)(NCS) (1), [Mn2(bzacen)2 (Me OH)2](C1O4)2 (2) and MnCl(bzacen) (3), have been synthesized and characterized by IR, Raman, electronic spectra and cyclic voltammetry. A structure determination of complexes 1 and 2 reveals a octahedral coordination with an N2O2 equatorial plane composed of atoms from the Schiff base ligand, while the Mn atom in complex 3 has square pyramidal coordination. The two MnN2O4 octahedra in complex 2 are joined by sharing two ketone oxygen atoms (Mn-O 1.910 and 2.493 Å) to form a dinuclear [Mn2(bzacen)2(MeOH)2]2+ cation, the Mn2O2 core having an Mn—Mn separation of 3.397 Å and Mn-O-Mn angles of 99.7°. In these three complexes v c=o and v c=c are shifted to lower frequencies in IR and Raman spectra; π-π∗ transitions, d-π∗ charge-transfer transitions and d-d∗ ligand field transitions are observed in electronic spectra." @default.
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- W2003206488 title "SYNTHESES AND CHARACTERIZATION OF THREE STRUCTURE TYPES FOR MANGANESE(III) COMPLEXES WITH<i>N,N′</i>-ETHYLENE<i>BIS</i>(1-PHENYL-3-IMINO-1-BUTANONE)" @default.
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- W2003206488 doi "https://doi.org/10.1080/00958979808022882" @default.
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