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- W2003223553 abstract "The effect of trace amounts of hydrogen bromide on the temperature and composition profiles through a series of lean, flat propane-oxygen flames diluted with argon has been examined. It is shown that the additive reduces the maximum rate of heat release in the flame, but this is reached at a lower temperature. The heat-release profile, however, is correspondingly broader, in that it is drawn out at the higher temperatures. In contrast, exothermic reactions become important at a lower temperature when the additive is present. This is confirmed by the composition profiles, which show that the additive enhances the disappearance of propane at the lower temperatures. These profiles have been used to calculate reaction-rate profiles. The maximum rates of consumption of propane and oxygen are reduced by the additive but, once again, these maximum rates are attained at a lower temperature. The maximum rate of formation of carbon dioxide, however, is unaffected by the hydrogen bromide, and it occurs at the same temperature. This latter reaction has been used to calculate hydroxyl radical concentrations and these are reduced by the additive. It is suggested that, with propane as fuel, the oxidation is promoted at the lower temperature levels through the reaction of bromine atoms with propane, and the subsequent inhibition is discussed in terms of the reaction of hydrogen atoms with the additive." @default.
- W2003223553 created "2016-06-24" @default.
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- W2003223553 date "1971-01-01" @default.
- W2003223553 modified "2023-09-23" @default.
- W2003223553 title "The effect of hydrogen bromide on the structure of propane-oxygen flames diluted with argon" @default.
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- W2003223553 doi "https://doi.org/10.1016/s0082-0784(71)80060-7" @default.
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