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- W2003226284 abstract "The reactions of M(PCy3)2 (3) (a, M = Pd; b, M = Pt; Cy = cyclohexyl) and trans-PtH2(PCy3)2 (4) with the α-ketoesters diethyloxomalonate (1) and ethylpyruvate (2) have been investigated. At room temperature 1 coordinates strongly to 3, whereas 2 yields labile adducts. At higher temperatures 2 reacts with 3b to yield the enolate trans-[Pt(PCy3)2(H){OCCHC(Me)(COOEt)OCO}] (8), the structure of which has been determined by X-ray diffraction. The ester 1 behaves like CO2 in undergoing rapid insertion into the PtH bond of 4. Unexpectedly reaction of 2 with 1 does not yield an insertion product, but again gives complex 8." @default.
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- W2003226284 date "1985-07-01" @default.
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- W2003226284 title "Palladium and platinum complexes of α-ketoesters. Crystal structure of trans-[Pt{P(C6H11)3}2(H){OO}]" @default.
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- W2003226284 doi "https://doi.org/10.1016/0022-328x(85)87421-0" @default.
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