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• W2003226739 startingPage "11147" @default.
• W2003226739 abstract "This report describes the structural and optical properties of a series of spherical shell/core nanoparticles in which the shell is comprised of a thin layer of gold, silver, or gold-silver alloy, and the core is comprised of a monodispersed silica nanoparticle. The silica core particles were prepared using the Stöber method, functionalized with terminal amine groups, and then seeded with small gold nanoparticles (approximately 2 nm in diameter). The gold-seeded silica particles were coated with a layer of gold, silver, or gold-silver alloy via solution-phase reduction of an appropriate metal ion or mixture of metal ions. The size, morphology, and elemental composition of the composite nanoparticles were characterized by field emission scanning electron microscopy (FE-SEM), energy-dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD), Fourier transform infrared (FT-IR) spectroscopy, thermal gravimetric analysis (TGA), dynamic light scattering (DLS), and transmission electron microscopy (TEM). The optical properties of the nanoparticles were analyzed by UV-vis spectroscopy, which showed strong absorptions ranging from 400 nm into the near-IR region, where the position of the plasmon band reflected not only the thickness of the metal shell, but also the nature of the metal comprising the shell. Importantly, the results demonstrate a new strategy for tuning the position of the plasmon resonance without having to vary the core diameter or the shell thickness." @default.
• W2003226739 created "2016-06-24" @default.
• W2003226739 creator A5012699591 @default.
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• W2003226739 date "2008-09-13" @default.
• W2003226739 modified "2023-10-12" @default.
• W2003226739 title "Preparation, Characterization, and Optical Properties of Gold, Silver, and Gold−Silver Alloy Nanoshells Having Silica Cores" @default.
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• W2003226739 doi "https://doi.org/10.1021/la8016497" @default.
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