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- W2003235513 abstract "Ionic liquids are shown to provide advantageous media for amineborane-based chemical hydrogen storage systems. Both the extent and rate of hydrogen release from ammonia borane dehydrogenation are significantly increased at 85, 90, and 95 degrees C when the reactions are carried out in 1-butyl-3-methylimidazolium chloride compared to analogous solid-state reactions. NMR studies in conjunction with DFT/GIAO chemical shift calculations indicate that both polyaminoborane and the diammoniate of diborane, [(NH3)2BH2+]BH4-, are initial products in the reactions." @default.
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- W2003235513 date "2006-05-28" @default.
- W2003235513 modified "2023-10-01" @default.
- W2003235513 title "Amineborane-Based Chemical Hydrogen Storage: Enhanced Ammonia Borane Dehydrogenation in Ionic Liquids" @default.
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- W2003235513 doi "https://doi.org/10.1021/ja062085v" @default.
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