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- W2003237071 abstract "Octaethyltetrathiaporphyrin dication, OTP2+, is electrochemically reduced by two successive electron-transfer processes to OPT0. OPT2+ forms intermolecular complexes with a series of π-donors. The association constants of the resulting complexes are controlled by the oxidation potentials of the π-donors and solvent properties. OTP2+ was incorporated into a Nafion membrane cast on a Pt electrode. Formation of OTP2+–π-donor complexes in the polymer membrane was followed by electrochemical and spectroscopic means. The association constants of the OTP2+–π-donor complexes in the Nafion membrane exhibit lower values than a homogeneous phase owing to the high ionic strength in the polyelectrolyte." @default.
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- W2003237071 date "1995-10-01" @default.
- W2003237071 modified "2023-10-05" @default.
- W2003237071 title "Molecular complexes between octaethyltetrathiaporphyrin dication and electron donors: A spectroscopic and electrochemical study" @default.
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- W2003237071 doi "https://doi.org/10.1002/poc.610081004" @default.
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